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Acrylonitrile is the starting material for the production of acrylic. This compound can be prepared from the reaction between propylene and nitric oxide based on the following chemical reaction:

____C3H6 (g) +___NO (g) → ___C3H3N (g) + ____H2O (g) + N2 (g)

If 126 g of C3H6 and 175 g NO were initially used, determine:


a. the limiting and excess reactants









b. the mass of acrylonitrile produced







c. the mass of excess reactant left



Sagot :

Solution (a)

Step 1: Write and balance the chemical equation.

4C₃H₆ + 6NO → 4C₃H₃N + 6H₂O + N₂

Step 2: Calculate the molar mass of each reactant.

For C₃H₆

molar mass = (12.01 g/mol × 3) + (1.008 g/mol × 6)

molar mass = 42.08 g/mol

For NO

molar mass = (14.01 g/mol × 1) + (16.00 g/mol × 1)

molar mass = 30.01 g/mol

Step 3: Determine the mole ratios needed.

For C₃H₆

mole ratio = 4 mol C₃H₆ : 4 mol C₃H₃N

For NO

mole ratio = 6 mol NO : 4 mol C₃H₃N

Step 4: Calculate the number of moles of C₃H₃N produced using the given masses of two reactants and their mole ratios.

Using C₃H₆

[tex]\text{moles of C₃H₃N = 126 g C₃H₆} × \frac{\text{1 mol C₃H₆}}{\text{42.08 g C₃H₆}} × \frac{\text{4 mol C₃H₃N}}{\text{4 mol C₃H₆}}[/tex]

[tex]\text{moles of C₃H₃N = 2.99 mol}[/tex]

Using NO

[tex]\text{moles of C₃H₃N = 175 g NO} × \frac{\text{1 mol NO}}{\text{30.01 g NO}} × \frac{\text{4 mol C₃H₃N}}{\text{6 mol NO}}[/tex]

[tex]\text{moles of C₃H₃N = 3.89 mol}[/tex]

Step 5: Determine the limiting and excess reactants.

Since C₃H₆ produces less number of moles of C₃H₃N

[tex]\boxed{\text{C₃H₆ is the limiting reactant.}}[/tex]

Since NO produces greater number of moles of C₃H₃N

[tex]\boxed{\text{NO is the excess reactant.}}[/tex]

Solution (b)

Step 1: Calculate the molar mass of C₃H₃N.

molar mass = (12.01 g/mol × 3) + (1.008 g/mol × 3) + (14.01 g/mol × 1)

molar mass = 53.06 g/mol

Step 2: Calculate the mass of C₃H₃N produced.

Since C₃H₆ is the limiting reactant

[tex]\text{mass of C₃H₃N = 2.99 mol C₃H₃N} × \frac{\text{53.06 g C₃H₃N}}{\text{1 mol C₃H₃N}}[/tex]

[tex]\boxed{\text{mass of C₃H₃N = 159 g}}[/tex]

Solution (c)

Step 1: Calculate the mass of NO consumed.

[tex]\text{mass of NO consumed = 2.99 mol C₃H₃N} × \frac{\text{6 mol NO}}{\text{4 mol C₃H₃N}} × \frac{\text{30.01 g NO}}{\text{1 mol NO}}[/tex]

[tex]\text{mass of NO consumed = 135 g}[/tex]

Step 2: Calculate the mass of NO left.

mass of NO left = initial mass of NO - mass of NO consumed

mass of NO left = 175 g - 135 g

[tex]\boxed{\text{mass of NO left = 40 g}}[/tex]

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