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Water wants to go down. ... Water trapped in aquifers deep inside the Earth sometimes comes into contact with sulfide-loaded rocks, like pyrite, Orndorff said. This creates sulfuric acid, which, with enough hydraulic pressure, can push up through the rock to carve out a cave
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Essentially, water reacts with carbon-dioxide to form carbonic acid. It then seeps slowly through the roof of the cave, depositing calcium carbonate, which hardens and builds up over time to form a stalactite.
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